Well, there is a great search function for most if not all of the modification questions. The fuel question is a good one. Its my understanding that running the octane that your motor needs is the seceret. When modifying the head, to add compression, your chances of pre-ignition increase. The added compression will ignite the fuel before the spark plug, causing a double fire, which interefere with each other. The results can be anywhere from a new noise to an engine failure.
Pump gas is pretty much junk anymore. The ethanol content really draws moisture, and there is no way to know, if the fuel is fresh fuel. All fuels degrade with exposure to heat, light and air, so its as important to run fresh, clean fuel as possible to have high enough octane for the new head mods.
Buying fuel with too high of an octane will not cause any damage to my knowledge, but will result in not using all of the potential of that fuel. It may actually hurt performance slightly. Oxygenated fuels are known to be more maintenance. The oxygenated parts are ethers, which evaporate quickly. When the ethers burn the by product is oxygen which is great for combustion. The maintenace comes in when you're done riding. Most guys will drain their fuel to capture as much of the performance as possible in their fuel cans. All Vp fuels come in a sealed metal container which seals their fuel to maintain all of its performance qualities. For the most part, a stock engine can live on pump gas with no issues. The freshness seem to be the important quality there. The shop altering your head should be qualified to also recommend a fuel octane. If you trust them with the head mod, then it should be easy enough to hear their advice about it. No matter what, keep your fuel protected. Out of the sun, in a sealed metal container, do not stock pile quanities, whatever you can do to keep it fresh and clean. They recommend going up 2 main sizes on both the main and slowjet. Thats probably the best way to jet anything start fat, and lean down until all bogging goes away. Too lean will definately melt her down. Do frequent plug checks, until you're positive that you got it right.
Camm II -110-leaded
Turbo Blue -110
Vp C12 -108-leaded non-oxygenated compression ratios under 15:1
Vp-u4.4 -103-leaded and oxygenated